How Light and Sound Waves Reveal Negative Pressure in Liquids

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Negative pressure is a rare and challenging-to-detect phenomenon in physics that occurs when the pressure of a liquid drops below zero. This can happen in a metastable state, where the liquid is trapped in a closed system and cannot expand or contract freely. In this state, the liquid is very sensitive to external perturbations and can collapse into a different state with a positive pressure. Scientists have developed an innovative method to study the metastable state of liquids with Minus pressure by encapsulating them in optical fibers. This technique provides a simpler way to measure pressure using light and sound waves, paving the way for new discoveries in thermodynamics and chemical reactions.

What is Negative Pressure and Why is it Important?

Pressure is defined as a force per unit area acting perpendicular to a surface of a solid, liquid, or gas. Normally, the pressure of a system is always positive, meaning that the force pushes against the walls of the container from the inside. For example, when you inflate a balloon, you increase the pressure of the air inside it.

However, liquids can exhibit a peculiar characteristic: they can exist in a specific metastable state corresponding to a Minus pressure value. In this state, the force pulls the walls of the container inward, creating a state of tension in the liquid. This can happen when the liquid is trapped in a closed system and cannot expand or contract freely, such as in a sealed glass capillary or a water droplet on a surface.

This pressure is important because it can affect the physical and chemical properties of liquids, such as their density, viscosity, boiling point, solubility, and reactivity. For example, water under negative pressure can freeze at higher temperatures than normal water. This pressure can also trigger phase transitions, such as cavitation (the formation of bubbles) or crystallization (the formation of solid structures). These phenomena can have practical applications in fields such as medicine, biology, engineering, and nanotechnology.

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a, Artist’s view of the LiCOF sample with a laser. b, Measured spectrum (blue) and simulation (red) of SBS spectrum with 1.125 μm core diameter. c, Geometry of the LiCOF sample spliced on both sides with a UHNA fibre for coupling and sealing. SMF is used for integrability. If the capillary is fully filled, the volume (V) stays constant (isochoric regime), whereas if a bubble is present, the pressure (P) stays constant (isobaric regime). d, Numerical simulations of the corresponding longitudinal, radially symmetric pressure acoustic modes L01, L02 and L03. Panel a credit: Long Huy Dao.

How to Create Negative Pressure in Liquids?

One way to create Minus pressure in liquids is to use optical fibers. Optical fibers are thin strands of glass or plastic that can transmit light along their length. They are widely used for communication and sensing applications. By filling an optical fiber with a liquid and sealing both ends, scientists can create a closed system where the liquid is confined by the walls of the fiber. By applying an external force or changing the temperature of the system, they can induce positive or negative pressure in the liquid.

Another way to create negative pressure in liquids is to use sound waves. Sound waves are vibrations that propagate through a medium, such as air or water. They can be generated by various sources, such as speakers or lasers. By applying sound waves to a liquid-filled optical fiber, scientists can create pressure variations along the length of the fiber. By adjusting the frequency and amplitude of the sound waves, they can control the magnitude and sign of the pressure in the liquid.

How to Measure Negative Pressure in Liquids?

One challenge of studying Minus pressure in liquids is how to measure it accurately and sensitively. Traditional methods, such as using gauges or sensors, are not suitable for measuring negative pressure in liquids because they can disturb or damage the system. Therefore, scientists have developed an innovative method that uses light and sound waves to measure negative pressure in liquids.

The method is based on the interaction of optical and acoustic waves in liquids. Optical waves are electromagnetic waves that carry light energy, such as visible light or infrared radiation. Acoustic waves are mechanical waves that carry sound energy, such as ultrasound or infrasound. When optical and acoustic waves meet in a medium, they can exchange energy and momentum through a process called Brillouin scattering. This process creates new optical and acoustic waves with different frequencies and amplitudes than the original ones.

By measuring the changes in the optical and acoustic waves due to Brillouin scattering, scientists can infer the properties of the medium, such as its density, elasticity, temperature, and pressure. In particular, they can measure Minus pressure in liquids by detecting how it affects the frequency shift and intensity ratio of the scattered optical and acoustic waves.

What are the Advantages of Using Light and Sound Waves to Measure Negative Pressure in Liquids?

The method of using light and sound waves to measure negative pressure in liquids has several advantages over other methods. First, it is non-invasive and non-destructive, meaning that it does not require physical contact with or damage to the system. Second, it is simple and fast, meaning that it does not require complex equipment or long processing time. Third, it is sensitive and precise, meaning that it can detect small changes in pressure with high resolution. Fourth, it is versatile and adaptable, meaning that it can be applied to different types of liquids with different properties.

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(From left to right) Research group leader Birgit Stiller in the lab with Andreas Geilen and Alexandra Popp. Credit: © Florian Ritter, MPL

What are the Applications of Studying Negative Pressure in Liquids?

Studying Minus pressure in liquids can have various applications in science and technology. For example, it can help to understand the fundamental aspects of thermodynamics, such as the stability and phase transitions of liquids. It can also help to explore the novel phenomena and functionalities of liquids under Minus pressure, such as supercooling, superheating, superfluidity, and superconductivity. Moreover, it can help to develop new techniques and devices that use liquids under negative pressure, such as microfluidics, nanofluidics, optofluidics, and acoustofluidics.

What are the Challenges and Future Directions of Studying Negative Pressure in Liquids?

Studying negative pressure in liquids also poses some challenges and limitations. For example, it is difficult to create and maintain Minus pressure in liquids for a long time, as they tend to relax to a positive pressure state due to external perturbations or internal fluctuations. It is also difficult to control and manipulate Minus pressure in liquids with high accuracy and flexibility, as they are influenced by many factors, such as temperature, viscosity, surface tension, and chemical composition. Furthermore, it is difficult to extend and generalize the results of studying negative pressure in liquids to other systems, such as solids or gases.

Therefore, future research on negative pressure in liquids should aim to overcome these challenges and limitations by developing new methods and materials that can enhance the stability, tunability, and applicability of Minus pressure in liquids. For instance, researchers could use nanomaterials or metamaterials that have special optical or acoustic properties to modify the behavior of liquids under negative pressure. They could also use hybrid systems that combine liquids with other phases or components to create new states of matter or functionality under negative pressure.

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Conclusion

Negative pressure is a rare and challenging-to-detect phenomenon in physics that occurs when the pressure of a liquid drops below zero. Scientists have developed an innovative method to study the metastable state of liquids with Minus pressure by encapsulating them in optical fibers and applying light and sound waves. This method provides a simpler way to measure pressure using Brillouin scattering, a process that creates new optical and acoustic waves with different frequencies and amplitudes than the original ones. By measuring the changes in the optical and acoustic waves due to Brillouin scattering, scientists can infer the properties of the liquid, such as its density, elasticity, temperature, and pressure.

Studying negative pressure in liquids can have various applications in science and technology, such as understanding the fundamental aspects of thermodynamics, exploring the novel phenomena and functionalities of liquids under Minus pressure, and developing new techniques and devices that use liquids under negative pressure.

However, studying Minus pressure in liquids also poses some challenges and limitations, such as creating and maintaining negative pressure in liquids for a long time, controlling and manipulating negative pressure in liquids with high accuracy and flexibility, and extending and generalizing the results of studying negative pressure in liquids to other systems. Therefore, future research on negative pressure in liquids should aim to overcome these challenges and limitations by developing new methods and materials that can enhance the stability, tunability, and applicability of negative pressure in liquids.

Read Original Article https://scitechdaily.com/negative-pressure-unveiled-the-dual-power-of-light-sound-waves/

References

  • Dao L.H., Geilen A., Popp A., et al. (2023). Brillouin scattering reveals negative liquid pressures. Nature Physics.
  • Max Planck Institute for the Science of Light (2023). Light and sound waves reveal negative pressure. ScienceDaily.
  • Bresme F., Oettel M., & Urbassek H.M. (2017). Negative pressures at fluid interfaces: Thermodynamics meets hydrodynamics. Advances in Colloid and Interface Science.
  • Zheng Q., & Pollack G.H. (2003). Long-range forces extending from polymer-gel surfaces. Physical Review E.
  • Baidakov V.G., & Kaverin A.M. (2012). Cavitation phenomena at positive or negative pressures in simple fluids: A review. Physics-Uspekhi.

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